i always get confused with what the positive and negative stand for but one is for ground and the other is the signal you want, you can probably just test it with alligator clips or something before you solder it. it might be obvious, the 'signal' in guitar effect pedals is almost always coming from the circuit board and the lead for 'ground' is coming from the power supply
just make sure in the end that the jack is wired so that the ground is going to the sleeve and that the signals are going to the tip:
in this diagram link.... 1 is sleeve(ground) and 3 is tip(signal)
http://upload.wikimedia.org/wikipedia/commons/thumb/9/93/Jack_plug.png/300px-Jack_plug.pngand i think you'll be able to put both Left and Right signals on the tip but if it interferes for some reason just go with one,
or eventually upgrade to two separate outs for Right and Left